From: Subject: POTASSIUM THIOCYANATE Date: Mon, 8 Dec 2008 10:52:21 -0500 MIME-Version: 1.0 Content-Type: multipart/related; type="text/html"; boundary="----=_NextPart_000_002A_01C95923.0BB616E0" X-MimeOLE: Produced By Microsoft MimeOLE V6.00.2900.5579 This is a multi-part message in MIME format. ------=_NextPart_000_002A_01C95923.0BB616E0 Content-Type: text/html; charset="Windows-1252" Content-Transfer-Encoding: quoted-printable Content-Location: http://www.jtbaker.com/msds/englishhtml/p6181.htm POTASSIUM THIOCYANATE

MSDS Number: P6181 * * * * * Effective Date: 11/21/08 * = * * * *=20 Supercedes: 01/25/06

POTASSIUM THIOCYANATE

1. Product Identification

Synonyms: Potassium sulfocyanate; Potassium = thiocyanide;=20 Thiocyanic acid, potassium salt; Potassium isothiocyanate
CAS = No.:=20 333-20-0
Molecular Weight: 97.18
Chemical = Formula: KSCN=20
Product Codes:
J.T. Baker: 3326, 5578
Mallinckrodt: = 7168=20

2. Composition/Information on Ingredients

  Ingredient  =
                              CAS No         Percent        Hazardous    =
                             =20
  ---------------------------------------   ------------   ------------  =
 ---------  =20
=20
  Potassium Thiocyanate                     333-20-0         90 - 100%   =
    Yes                                                                  =
 =20
=20

3. Hazards Identification

Emergency Overview
--------------------------=20
WARNING! HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO = SKIN,=20 EYES AND RESPIRATORY TRACT. =

SAF-T-DATA^(tm)=20 Ratings (Provided here for your convenience)=20 =
---------------------------------------------------------------------= --------------------------------------=20
Health Rating: 2 - Moderate (Life)
Flammability Rating: 0 - = None=20
Reactivity Rating: 1 - Slight
Contact Rating: 2 - Moderate =
Lab=20 Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES =
Storage=20 Color Code: Green (General Storage)=20 =
---------------------------------------------------------------------= --------------------------------------=20

Potential Health Effects =
----------------------------------=20

Inhalation:
Causes irritation to the respiratory = tract.=20 Symptoms may include coughing, shortness of breath. =
Ingestion:=20
May cause psychosis, vomiting, disorientation, weakness, low blood = pressure, convulsions and death which may be delayed. The probable = lethal dose=20 is between 15-30 grams.
Skin Contact:
Causes irritation = to=20 skin. Symptoms include redness, itching, and pain.
Eye = Contact:=20
Causes irritation, redness, and pain.
Chronic Exposure: =
Prolonged or repeated skin exposure may cause dermatitis. Repeated = ingestion of small amounts may cause weakness, confusion, central = nervous=20 system effects, nausea and skin eruptions.
Aggravation of = Pre-existing=20 Conditions:
No information found.

4. First Aid Measures

Inhalation:
Remove to fresh air. If not = breathing, give=20 artificial respiration. If breathing is difficult, give oxygen. Get = medical=20 attention.
Ingestion:
Induce vomiting immediately as = directed=20 by medical personnel. Never give anything by mouth to an unconscious = person.=20 Get medical attention.
Skin Contact:
Wipe off excess = material=20 from skin then immediately flush skin with plenty of water for at = least 15=20 minutes. Remove contaminated clothing and shoes. Get medical = attention. Wash=20 clothing before reuse. Thoroughly clean shoes before reuse.
Eye = Contact:
Immediately flush eyes with plenty of water for at = least 15=20 minutes, lifting lower and upper eyelids occasionally. Get medical = attention=20 immediately.

5. Fire Fighting Measures

Fire:
Not considered to be a fire hazard.=20
Explosion:
Not considered to be an explosion hazard.=20
Fire Extinguishing Media:
Use any means suitable for=20 extinguishing surrounding fire.
Special Information:
In = the=20 event of a fire, wear full protective clothing and NIOSH-approved=20 self-contained breathing apparatus with full facepiece operated in the = pressure demand or other positive pressure mode. May emit toxic and = flammable=20 fumes of cyanide if involved in a fire.

6. Accidental Release Measures

Ventilate area of leak or spill. Wear appropriate personal=20 protective equipment as specified in Section 8. Spills: Sweep up and=20 containerize for reclamation or disposal. Vacuuming or wet sweeping = may be=20 used to avoid dust dispersal.

7. Handling and Storage

Keep in a tightly closed container, stored in a cool, dry,=20 ventilated area. Protect against physical damage. Isolate from = oxidizing=20 materials. Store in the dark. Containers of this material may be = hazardous=20 when empty since they retain product residues (dust, solids); observe = all=20 warnings and precautions listed for the product.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits:
None established.=20
Ventilation System:
A system of local and/or general = exhaust is=20 recommended to keep employee exposures as low as possible. Local = exhaust=20 ventilation is generally preferred because it can control the = emissions of the=20 contaminant at its source, preventing dispersion of it into the = general work=20 area. Please refer to the ACGIH document, Industrial Ventilation, A = Manual=20 of Recommended Practices, most recent edition, for details.=20
Personal Respirators (NIOSH Approved):
For conditions = of use=20 where exposure to dust or mist is apparent and engineering controls = are not=20 feasible, a particulate respirator (NIOSH type N95 or better filters) = may be=20 worn. If oil particles (e.g. lubricants, cutting fluids, glycerine, = etc.) are=20 present, use a NIOSH type R or P filter. For emergencies or instances = where=20 the exposure levels are not known, use a full-face positive-pressure,=20 air-supplied respirator. WARNING: Air-purifying respirators do not = protect=20 workers in oxygen-deficient atmospheres.
Skin Protection: =
Wear=20 impervious protective clothing, including boots, gloves, lab coat, = apron or=20 coveralls, as appropriate, to prevent skin contact.
Eye = Protection:=20
Use chemical safety goggles and/or full face shield where dusting = or=20 splashing of solutions is possible. Maintain eye wash fountain and=20 quick-drench facilities in work area.

9. Physical and Chemical Properties

Appearance:
Colorless, deliquescent crystals.=20
Odor:
Odorless.
Solubility:
Very soluble = in=20 water.
Density:
1.89
pH:
No information = found.=20
% Volatiles by volume @ 21C (70F):
0
Boiling = Point:=20
500C (932F)
Melting Point:
173C (343F)
Vapor = Density=20 (Air=3D1):
No information found.
Vapor Pressure (mm = Hg):=20
No information found.
Evaporation Rate (BuAc=3D1): =
No=20 information found.

10. Stability and Reactivity

Stability:
Stable under ordinary conditions of = use and=20 storage. Slowly decomposes on exposure to light.
Hazardous=20 Decomposition Products:
Burning may produce nitrogen oxides, = sulfur=20 compounds, and possibly cyanides.
Hazardous Polymerization: =
Will not occur.
Incompatibilities:
Strong = oxidizers, active=20 halogen compounds.
Conditions to Avoid:
Light and=20 incompatibles.

11. Toxicological Information

Oral rat LD50: 854 mg/kg. Investigated as a mutagen,=20 reproductive effector.

  --------\Cancer =
Lists\------------------------------------------------------
                                         ---NTP Carcinogen---
  Ingredient                             Known    Anticipated    IARC =
Category
  ------------------------------------   -----    -----------    =
-------------
  Potassium Thiocyanate (333-20-0)        No          No            None

12. Ecological Information

Environmental Fate:
No information found.=20
Environmental Toxicity:
No information found. =

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be = managed in an appropriate and approved waste disposal facility. = Processing,=20 use or contamination of this product may change the waste management = options.=20 State and local disposal regulations may differ from federal disposal=20 regulations. Dispose of container and unused contents in accordance = with=20 federal, state and local requirements.

14. Transport Information

Not regulated.

15. Regulatory Information

  --------\Chemical Inventory Status - =
Part 1\---------------------------------
  Ingredient                                       TSCA  EC   Japan  =
Australia
  -----------------------------------------------  ----  ---  -----  =
---------
  Potassium Thiocyanate (333-20-0)                  Yes  Yes   Yes      =
Yes                                     =20
=20
  --------\Chemical Inventory Status - Part =
2\---------------------------------
                                                          --Canada--
  Ingredient                                       Korea  DSL   NDSL  =
Phil.
  -----------------------------------------------  -----  ---   ----  =
-----
  Potassium Thiocyanate (333-20-0)                  Yes   Yes   No     =
Yes            =20
=20
  --------\Federal, State & International Regulations - Part =
1\----------------
                                             -SARA 302-    ------SARA =
313------
  Ingredient                                 RQ    TPQ     List  =
Chemical Catg.
  -----------------------------------------  ---   -----   ----  =
--------------
  Potassium Thiocyanate (333-20-0)           No    No      Yes        No
=20
  --------\Federal, State & International Regulations - Part =
2\----------------
                                                        -RCRA-    -TSCA-
  Ingredient                                 CERCLA     261.33     8(d)=20
  -----------------------------------------  ------     ------    ------
  Potassium Thiocyanate (333-20-0)           No         No         No    =
      =20
=20
=20
Chemical Weapons Convention:  No     TSCA 12(b):  No     CDTA:  No
SARA 311/312:  Acute: Yes      Chronic: Yes  Fire: No  Pressure: No
Reactivity: No          (Pure / Solid)=20

Australian Hazchem Code: None allocated.=20
Poison Schedule: None allocated.
WHMIS:
This = MSDS=20 has been prepared according to the hazard criteria of the Controlled = Products=20 Regulations (CPR) and the MSDS contains all of the information = required by the=20 CPR.

16. Other Information

NFPA Ratings: Health: 3 Flammability: 0 = Reactivity: 0
Label Hazard Warning:
WARNING! = HARMFUL IF=20 SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY = TRACT.=20
Label Precautions:
Avoid contact with eyes, skin and=20 clothing.
Wash thoroughly after handling.
Avoid breathing = dust.
Keep=20 container closed.
Use only with adequate ventilation.
Label = First=20 Aid:
If swallowed, induce vomiting immediately as directed by = medical=20 personnel. Never give anything by mouth to an unconscious person. In = case of=20 contact, wipe off excess material from skin then immediately flush = eyes or=20 skin with plenty of water for at least 15 minutes. Remove contaminated = clothing and shoes. Wash clothing before reuse. If inhaled, remove to = fresh=20 air. If not breathing, give artificial respiration. If breathing is = difficult,=20 give oxygen. In all cases, get medical attention.
Product = Use:=20
Laboratory Reagent.
Revision Information:
No = Changes.=20
Disclaimer:=20 =
*********************************************************************= ***************************=20
Mallinckrodt Baker, Inc. provides the information contained = herein in=20 good faith but makes no representation as to its comprehensiveness or=20 accuracy. This document is intended only as a guide to the appropriate = precautionary handling of the material by a properly trained person = using this=20 product. Individuals receiving the information must exercise their = independent=20 judgment in determining its appropriateness for a particular purpose.=20 MALLINCKRODT BAKER, INC. MAKES NO REPRESENTATIONS OR WARRANTIES, = EITHER=20 EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF=20 MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE=20 INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION = REFERS.=20 ACCORDINGLY, MALLINCKRODT BAKER, INC. WILL NOT BE RESPONSIBLE FOR = DAMAGES=20 RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION.=20 =
*********************************************************************= ***************************=20
Prepared by: Environmental Health & Safety
Phone = Number:=20 (314) 654-1600 (U.S.A.)

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